For the first time, engineers have utilized a single enzyme biomineralization process to create a catalyst that uses the energy of captured sunlight to split water molecules to produce hydrogen. The synthesis process is performed at room temperature and under ambient pressure, overcoming the sustainability and scalability challenges of previously reported methods. Solar-driven water splitting is a promising route towards a renewable energy-based economy. The generated hydrogen could serve as both a transportation fuel and a critical chemical feedstock for fertilizer and chemical production. Both sectors currently represent a large fraction of total greenhouse gas emissions. One of the challenges to realizing the promise of solar-driven energy production is that, while the required water is an abundant resource, previously-explored methods utilize complex routes that require environmentally-damaging solvents and massive amounts of energy to produce at large scale. The expense and harm to the environment have made these methods unworkable as a long-term solution. Now, a team of engineers has harnessed a biomineralization approach to synthesizing both quantum confined nanoparticle metal sulfide particles and the supporting reduced graphene oxide material to create a photocatalyst that splits water to form hydrogen.
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